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MATERIAL
SAFETY DATA SHEET
PRODUCT: PHOSPHORIC ACID
|
SECTION 1 |
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CHEMICAL IDENTIFICATION |
|
Trade name |
: |
Phosphoric Acid |
|
Chemical Name |
: |
Phosphoric Acid |
|
Synonyms |
: |
Orthophosphoric
Acid, Monophosphoric acid |
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SECTION 2 |
|
COMPOSITION AND INFORMATION ON INGREDIENTS |
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CAS NO. |
: |
7664-38-2 |
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H S Code |
: |
2809 20 01 |
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UN Code |
: |
UN 1805 |
SECTION 3 Appearance &
Odour : Clear,colourless, syrupy liquid with no odour. Safety Information : Health Effects : Corrosive liquid causes eye and skin burns. Physical &
Chemical : Forms flammable & Explosive hydrogen through corrosion of metals. Hazards At high
temperature : Thermal
decomposition giving corrosive products. Specific Hazards : Corrosive causes eye and skin burns. SECTION 4 General Advice : Take off
immediately all contaminated clothing (Including Shoes) Inhalation : Move to fresh air.
If required, provide oxygen or artificial respiration. Hospitalize. Skin contact : Wash immediately,
abundantly & thoroughly with water. If possible rinse with bicarbonate
solution. Eye contact : Wash immediately
& abundantly with water for at least 15 minutes. Consult an
ophthalmologist immediately. After swallowing : Do not induce
vomiting, rinse mouth and lips with plenty of water if the subject is
conscious, then hospitalize immediately. Never give anything in mouth to an
unconscious person. SECTION 5 Suitable
Extinguishing media : Incase of Fire
nearby use dry Powder, Foam, Carbon dioxide( CO2) media Special hazards : Non-flammable
product. Forms flammable and explosive hydrogen through corrosion of Metals.
Temperature above
200 0C: Formation of Polyphosphoric Acid (Dehydration)
At High
Temperature: Thermal decomposition giving
corrosive products:
Phosphorus Oxides. Specific Methods : In case of Fire:
remove exposed containers. Special Protective
Equipment for Firefighters : Personal Protection : Avoid contact with
skin and eyes and inhalation of hot vapours. Environmental
protection : Do not allow
material to be released to the environment. Do not let the product enter into
drains. Contain by damming. Methods for cleaning up
: - Recovery : Pump into an inert labeled emergency
container. Neutralization : Technical measures/
Precautions : Safe handling
advice : Avoid splashing when handling. Do not pour water Storage : Technical measures/
Storage information : Keep containers
tightly closed in a cool, well-ventilated place. Storage information Store in
well-insulated area. Store protected from moisture & heat. Keep at temperature
above 16 0 C Provide a catch-tank & an impermeable corrosion
resistant floor with drainage to a
neutralization tank within a bunked area. Provide anti-corrosion electrical
equipment. Incompatible
Products : Bases-Quicklime Alcohols-Ketones-Amines Water Nitrates-Chlorates-Calcium
Carbide Metals-Finely
divided metals Combustible
Material : - Recommended : Stainless steel 316
L-Carbon Steel ( Vulcanized Rubber coated Steel) Plastic Materials (Polyurethane)
Small Quantities: Glass protected by a fitted metallic
covering To be avoided : Metals: Ordinary Steel, Copper,
Aluminum, (and
alloys) Personal Protectective Equipment Respiratory
protection : In case of
insufficient ventilation, wear suitable respiratory equipment Hand protection : Gloves Eye protection : Safety glasses /
goggles. Face mask (in case of spattering) Skin & body
protection Protective clothing
Non-skid boots
(Butyl rubber-chlorinated polyethylene-Neoprene-Polyvinyl Chloride) Specific hygienic
Measures : Avoid contact with
skin and eyes and inhalation of hot vapours Colourless Odour : none Specific gravity : Solubility in Water
: at 20 ° C Completely soluble Solvents : Soluble in
Alcohols Conditions to avoid : Store protected
from moisture & heat Materials to avoid : Bases, Quicklime:
Exothermic reaction-Violent reaction Alcohols- ketones
-Amines: Exothermic reaction Water: Very
exothermic reaction & possibility of spitting Nitrates-Chlorates
– Calcium Carbide: Explosive reaction (Flammability) Metals – finely
divided metals Combustible
materials: Overheating and ignition Hazardous
Decomposition products : Not known : Acute toxicity : Inhalation : Chronic Effects : Target Organ(S):
Liver, Blood, Bone Marrow Additional
toxicological information : To the best of our
knowledge the acute and chronic toxicity of this substance is not fully
known. No classification data on carcinogenic properties of this material is
available from the EPA, IARC, NTP, OSHA or ACGIH. : Phosphoric Acid is
practically nontoxic to one species of fresh water fish. No toxicity data was
available for other freshwater species. Disposal of the
Product : Recommendation
:Consult state, local or national regulations for proper disposal.
Dilute cautiously
with water and then process.
Neutralize with an
alkaline carbonate or
Neutralize with
slaked lime (Filter the salt obtained- Neutralize theliquid)
Recommendation : Disposal must be
made according to official regulations. : UN number : UN 1805 Description of
goods : Phosphoric Acid ADR/RID/IMOclass : 8 Packing group : III IATA Class : European
Information : Corrosive S 36/37/39 Wear
Suitable Protective Clothing, Gloves And Eye/Face Protection.
: The above
information is believed to be correct but does not purport to be
all-inclusive and shall be used only as a guide. Star Chemicals (Bombay) Pvt
Ltd shall not be held liable for any damage resulting from handling or from
contact with the above product. Product
Range MSDS
HAZARDS IDENTIFICATION
FIRST-AID MEASURES
FIRE FIGHTING MEASURES
Incase of Fire: wear a self-contained
breathing
apparatus and Acid
resistant clothing.
SECTION 6
ACCIDENTAL RELEASE MEASURES
Dilute cautiously with water &
then process.
Neutralize with an alkaline carbonate
or neutralize
with slaked lime ( Filter the salt
obtained –neutralize
the liquid)
SECTION 7
HANDLING AND STORAGE
Storage & handling precautions
applicable to
products:
Corrosive: Ensure appropriate exhaust &
ventilation at
machinery. Provide showers, eye
baths.
SECTION 8
EXPOSURE CONTROL/PERSONAL PROTECTION
Protective
Provisions
:
Ensure sufficient
air exchange and/ or exhaust in working areas
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
Physical State (
20° C)
:
Liquid
(viscous)
Colour
:
Liquid (25 ° C) 1.5-1.7 depending
upon Phosphoric
acid strength
SECTION 10
STABILITY AND REACTIVITY
SECTION 11
TOXICOLOGICAL INFORMATION
May be harmful by inhalation, ingestion, or
skin absorption. Material is destructive to tissue of the mucous membranes
and upper respiratory tract, eyes and skin.
Inhalation may result in spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Symptoms
of exposure may
include burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea and vomiting.
SECTION 12
ECOLOGICAL INFORMATION
SECTION 13
DISPOSAL CONSIDERATIONS
SECTION 14
TRANSPORT INFORMATION
:
8
SECTION 15
REGULATORY INFORMATION
SECTION 16
OTHER INFORMATION
|| Red Phosphorus
|| Phosphorus
Pentasulphide || Phosphoric
Acid || Super
Phosphoric Acid || Polyphosphoric
Acid ||
|| Yellow Phosphorus
|| Ferro Phosphorus
||
Applications
|| Red Phosphorus
|| Phosphorus Pentasulphide
||
|| Red Phosphorus
|| Phosphorus Pentasulphide
|| Phosphoric Acid
|| Super Phosphoric
Acid || Polyphosphoric
Acid ||
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